Services - Café Thorium

Services - Café Thorium
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Café Thorium Radioanalytical Facility
We provide analytical support for the detection of natural and man-made radionuclides in environmental samples. Special emphasis will be placed upon those isotopes that are used as tracers of marine process, and are commonly measured by detection of gamma, beta and alpha counting techniques. Also
SPECIAL OFFER 50L
open seawater samples available (See
Sample Archive
tab)!
Services
Equipment
Pricing
Sample Archive
Methods and Technologies
Services
Typical measurements and services offered
Sediments by gamma spectrometry
The largest use of the facility is the analyses of gamma emitting radionuclides in marine sediments. Dried and ground sediment samples are placed in calibrated counting jars on the gamma counter for 12-48 hours. From measurement of isotopes such as 210Pb, 226Ra, 234Th, 137Cs and 7Be, one can often calculate the rates of mixing (bioturbation and physical mixing) and sedimentation in coastal and deep ocean sediments, on time scales of days to 100 years.
Water, particles, sediment traps for 234Th
Thorium-234 is a particle-reactive naturally occurring decay product of uranium-238. Measurement of the difference in 234Th and 238U activities in seawater provides an in-situ tracer of particle export and cycling in the upper ocean on time scales of days-weeks. Detection of 234Th can be accomplished via beta or gamma methods depending upon sample size and application. This approach is becoming a "core" measurement in many biogeochemical studies.
Groundwater and coastal waters for radium isotopes
The radium isotopes 226Ra (t1/2 1620 years), 228Ra (t1/2 5.75 years), 224Ra (t1/2 3.66 days), and 223Ra (t1/2 11.4 days), are naturally produced in sediments and are highly soluble and enriched in groundwater and coastal surface waters. As such, measurement of the flux of Ra out of sediments can be used to quantify groundwater discharge, and measurement of surface water Ra gradients can be used to quantify flow and horizontal mixing processes in the coastal ocean. Recently pioneered methods by Dr. W. Moore (U. So. Carolina) now allow for the rapid detection of 223Ra and 224Ra using a customized delayed coincidence counter. 226Ra and 228Ra are efficiently detected using a gamma "well" detector.
Specialized Services
In addition to the above mentioned radiation detection services, we anticipate some use of the Café Thorium facility for more complicated radiochemical purification and sampling activities. These could include on a cost-per-sample basis, the following two services or we could discuss the development of other techniques:
Radiochemistry for Plutonium
Many studies of the man-made and natural radionuclides, involve the radiochemical purification of the isotope of interest prior to alpha, beta or gamma counting. One such element is plutonium, which was introduced to the environment primarily from atmospheric nuclear weapons testing in the 1960's. This tracer is often used in marine sciences to constrain sedimentation and mixing rates in sediments (in addition to 210Pb measured via gamma counting). The Café Thorium facility can analyze for Pu isotopes.
Sampling preparation & consultation- water 234Th
We have provided 234Th "sampling kits" for scientists interested in using this tracer in their own biogeochemical study, which enable the researcher to collect 234Th samples (using pre-packaged filtration and Thorium specific adsorbers) that are mailed back to WHOI for immediate analyses. Such arrangements would be made on an individual request basis.
Particulate Inorganic Carbon
NEW we are able to analyze sediment and filters for PIC by coulometer. Please write jdrysdale@whoi.edu with inquiries.
Equipment
Erin Black inserting a sample into a gamma detector. 2012.
Gamma Detectors, Planar Design
We have two Canberra
(now
Mirion Technologies
model GL2020RS
low energy Germanium
(LeGe) planar detectors coupled with low background cryostats in low background shields. These have 2000mm2 active area crystals with a detection range from 10 kiloelectron volts(keV) to 1200 keV. Our detectors have been used regularly to detect 210Pb or 234Th in sediments and 7Be from rainwater. With their large surface area and low background, these detectors are useful to anyone who is trying to detect environmental levels of a gamma emitting radioisotope in either a liquid or solid matrix. Samples are generally placed in 8 ounce polystyrene jars, set on top of the Ge crystal, and gamma events are counted. Since the detectors will accumulate a full spectrum of identifiable gamma peaks within each counting period, multiple radionuclides can be quantified during a single count. These instruments are coupled with Windows-based spectroscopy software by Aptec, for data processing.
Gamma Detectors, Well Design
The facility operates 2 Canberra closed-end coaxial large volume well detectors.  Both detectors have a 4p counting geometry, a detection range past 3000keV and are coupled with low background cryostats and shields. In order to reduce background, detectors GCW4023S3 and GCW4030S use a large plastic scintillator detector and coincidence timing circuit to create an anti-coincidence veto gate suitable for both germanium detectors.  Either APTEC PCMCA or Canberra Genie 2000/LYNX are used as processing MCA software.  These well detectors are the most sensitive gamma counter designs available, thus providing high quality data and minimizing counting time.
The facility was selected as a beta testing site for Canberra Industries and in 2013 the facility acquired a next generation Canberra SAGe well detector with a larger crystal which provides greater efficiency and superior energy resolution compared with our other 28 mm wells.
Ken with Beta detectors
Beta Detectors, Gas Flow Proportional Counters
We have 6 Riso GM-25-5, five sample low-level beta detectors. These accept any samples that can be mounted on a 25mm filter holder. These detectors have very low backgrounds, 0.17 counts per minute, and can have counting efficiencies as high as 55%. Beta particle detection is not readily nuclide specific so there can be some sample purification necessary before counting. These detectors count five samples at a time using Windows-based software designed by Riso in Denmark. They are ideal for all beta detection except for the weakest beta emitters (3H and 14C), which cannot penetrate the mylar window into the counting chamber.
Alpha Detectors, Surface Barrier
Alpha analysis is conducted via CANBERRA’s Alpha Analyst  with an eight Passivated Implanted Planar Silicon (PIPS) detectors.  Operating through Genie 2000,  Apex-Alpha™ software controls detector set-up and calibration, quality assurance, sample analysis and reporting.  Alpha decay occurs in the elements of higher atomic number and the alpha particles high energy and short travel requires some chemical purification and electroplating, precipitating or evaporation onto a metal disc for counting. These have traditionally been used for plutonium, long-lived thorium isotopes and other actinides.  The facility can do these purification and plating steps if needed.
Delayed Coincidence Counting System
The short-lived 223Ra and 224Ra isotopes can be counted using a delayed coincidence alpha scintillation techniques. Samples are collected by passing 1092s liters of seawater through MnO2-impregnated fibers which are partially dried and placed in a scintillation cell attached to a photo multiplier tube. Inert gas is recirculated through the system and the gaseous Radon daughters rapidly reach equilibrium with the parent Ra on the fiber. The detector discriminates between the alpha decay of the short-lived daughters of 223Ra and 224Ra via delayed coincidence counting techniques. Two of these systems are available as part of the facility.
Large well gamma detector
Sediments by Gamma Spectrometry
One of the largest uses of the facility is for the analyses of gamma emitting radionuclides in marine sediments. Dried and ground sediment samples are placed in calibrated counting jars on the planar and well gamma counters for 12-48 hours. From measurement of isotopes such as 210Pb, 226Ra, 234Th, 137Cs and 7Be, one can often calculate the rates of mixing (bioturbation and physical mixing) and sedimentation in coastal and deep ocean sediments, on time scales of days to 100 years.
Water, Particles, Sediment Traps for 234Th
Thorium-234 is a particle-reactive naturally occurring decay product of uranium-238. Detection of 234Th can be accomplished via beta or gamma methods depending upon sample size and application.  Measurement of the difference in 234Th and 238U activities in seawater provides an in-situ tracer of particle export and cycling in the upper ocean on time scales of days-weeks. This approach is becoming a "core" measurement in many biogeochemical studies.  Additional alpha spectrometry is often performed to evaluate chemical yields from extraction procedures as well as for specific actinide analysis in marine and ground water samples.
CO2 coulometer (CM5014, UIC Inc)
In short the coulometer contains a cell filled with a monoethanolamine solution and pH indicator and is placed between a light source and photodetector. Upon release CO2 is adsorbed by the monoethanolamine to form a titratable acid causing the indicator to fade. The photodetector monitors the change of the color as a percent transmittance from the baseline. The amount of energy used to then neutralize the reaction using Faraday’s Law allows for a calculation of CO2 concentration (1 faraday of electricity results in the alteration of 1 gram equivalent weight of a substance during electrolysis).
Groundwater and Coastal Waters for Radium Isotopes
The radium isotopes 226Ra (t1/2 1620 years), 228Ra (t1/2 5.75 years), 224Ra (t1/2 3.66 days), and 223Ra (t1/2 11.4 days), are naturally produced in sediments and are highly soluble and enriched in groundwater and coastal surface waters. As such, measurement of the flux of Ra out of sediments can be used to quantify groundwater discharge, and measurement of surface water Ra gradients can be used to quantify flow and horizontal mixing processes in the coastal ocean. Current methods now allow for the rapid detection of 223Ra and 224Ra using a customized delayed coincidence counter. 226Ra and 228Ra are efficiently detected using a gamma "well" detector.
Genie Software – gamma detector spetra.
Results showing Cs134 peak
Gamma detector
Pricing
Analytical charges are made on a per sample basis and reflect the cost of doing the measurements. Please contact us at
spike@whoi.edu
for
radiochemical analysis
(with a cc to
jdrysdale@whoi.edu
) regarding scheduling, sample submission and sampling protocols/requirements. Samples  for gamma spectrometry should arrive processed, ground/homogenized, dry and ready for analysis. Properly sized vials can be provided. Please contact us regarding specific needs for your samples. Contact jdrysdale@whoi.edu regarding PIC analysis.
Sample prices below are for calendar year 2023. We apologize for the increases but they are in part driven by increasing overhead costs.
Analysis Type
Price
Gamma spectrometry counting
$388 per sample
Beta spectrometry counting
$388 per 5 samples
Specialized services & PIC
please contact us
Notes:
There is an added approximately 65% institutional overhead charge on these prices. (this is related to the WHOI MTDC overhead cost recovery structure, please contact us for the actual rates). Please direct inquiries to
spike@whoi.edu
. Sample acquisition and shipping costs are borne by the client. Note that samples containing radioisotopes above environmental background may require special handling and analysis. Please contact us to discuss your options.
Good results require good samples, we can assist you in mounting an effective sampling program . Please contact Ken Buesseler (
kbuesseler@whoi.edu
) for information.
Sample Archive
Archive 50L Seawater Samples
Café Thorium has archived the remains of what was once the largest collection of large volume(50 liter) open ocean water samples in the world. These were collected mostly between 1962 and 1987 with Bodman samplers or the ship’s clean seawater intake. Most have been disposed of due to lack of storage space and these last 750 cannot be stored indefinitely. If you have an interest in analyzing any of these please contact Jessica Drysdale (jdrysdale@whoi.edu). They can be yours for $25 handling plus the cost of shipping and an acknowledgement in any published results.
Excel file of sample details
Really want these samples?
Click here to download specific sample information including location coordinates, sampling date, ship, cruise and station numbers.
Sample List
Methods and Technologies
CMER-Rio5 Methods Cookbook
An online methods "cookbook" of methods for analyzing samples for a variety of radionuclides from laboratories around the world. We are always excited to include new methods!
Neutrally Buoyant Sediment Traps
A novel sediment trap fixed to a neutrally buoyant float that drifts with currents catching particles as they descend through the water column. More information about their use and development can be found
HERE.
Minions
A small, inexpensive device to be deployed throughout to ocean to take photos of falling carbon particles (
marine
snow). Ballasted to sink to a specific depth and neutrally buoyant to drift with currents a Minion is short for MINiature IsOpycNal float. Current information can be found with the
Ocean Twilight Zone
as well as in this
Oceanus
article "
Chasing Ocean Snowflakes
." More information to come.